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By Bennett R., Bowers R. G.

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Th. G. (1986) K. Ned. Akad. Wet. Ser. B 89:61 21. Hunter R. J. (1993) Introduction to Modern Colloid Science. Oxford University Press, Oxford 22. Seddon J. M. (1996) Ber. Bunsen. Phys. Chem. 100:380 23. Hoar T. , Schulman J. H. (1943) Nature 152:102 24. Bancroft W. , Tucker C. W. (1927) J. Phys. Chem. 31:1681 25. Scriven L. E. (1976) Nature 263:123 26. , Strey R. (1988) J. Phys. Chem. 92:2294 27. Helfrich W. (1973) Z. Naturforsch. C 28:693 28. , Lipowsky R. (1999) Phys. Rev. Let. 82:221 29. , Binks B.

The polymeric phase is presented by the lighter contrast. Reproduced from [77]. Copyright (1995) American Chemical Society. Figure 14 shows the network formation as a function of time in a sample prepared of 30 wt% water, 32 wt% MMA, 38 wt% (((acryloyloxy)undecyl)dimethylammino) acetate (AUDMAA), a polymerisable zwitterionic surfactant, and 2 wt% cross-linking agent (ethylene glycol dimethacrylate) [77]. Numerous nanoparticles can be seen from the TEM micrograph after 3 min of polymerisation, when the sample is still very fluid.

The crystallisation was performed within one week. At w0 = 10, a non-compact fibre formed, consisting of 2–20 μm long multiple filaments, while for 12 ≤ w0 ≤ 29 single highly ordered crystalline barrite filaments 1–100 μm long and 20–200 nm wide were obtained. All filaments formed in this w0 -range were found to be single crystalline and elongated predominately along the [010] crystallographic axis displaying a uniform thickness and aspect ratio of 1000. These results indicate that the final morphology is not determined by the microemulsion template.

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