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M Nakamura, GL Bertrand, SE Friberg. J Colloid Interface Sci 91:516–524 (1983). 47. G Olofsson, J Kizling, P Stenius. J Colloid Interface Sci 111:213–222 (1986). 48. G Haandrikman, GJR Daane, FJM Kerkhof, NM van Os, LAM Rupert. J Phys Chem 96:9061–9068 (1992). 49. G Gu, W Wang, H Yan. J Colloid Interface Sci 167:87–93 (1994). 50. K Mukherjee, DC Mukherjee, SP Moulik. J Colloid Interface Sci 187:327–333 (1997). 51. A D’Aprano, A Lizzio, V Turco Liveri. J Phys Chem 91:4749–4751 (1987). 52. V Arcoleo, M Goffredi, G La Manna, F Aliotta, ME Fontanella.

Step in the specific heat 24 27 27 27 29 31 34 39 41 III. Phase Separation Kinetics A. Energy barrier B. Experimental observation of oscillations C. Mechanism of phase separation D. Temperature dependence of the droplet–droplet distance 43 43 45 47 48 IV. Conclusion 54 References 56 23 24 Vollmer I. INTRODUCTION Mixtures containing surfactants and hydrophilic (for instance, water) and hydrophobic (for instance, alkanes) components show a fascinating thermodynamic and kinetic behavior. Gaining an understanding of this behavior poses a large variety of interesting physical and chemical challenges, which have been a focus of fundamental research in colloid science throughout recent decades.

Biochim Biophys Acta 947:209– 246 (1988). 20. V Arcoleo, F Aliotta, M Goffredi, G La Manna, V Turco Liveri. Mater Sci Eng C5: 47–53 (1997). 21. V Turco Liveri. In: Current Topics in Solution Chemistry, Vol 2. ), Research Trends, Trivandrum, 1997, pp. 143–156. 22. P Linse. J Chem Phys 90:4992–5004 (1989). Solutions of Reversed Micelles 21 23. G Giammona, F Goffredi, V Turco Liveri, G Vassallo. J Colloid Interface Sci 154: 411–415 (1992). 24. R Day, BH Robinson, J Clarke, J Doherty. J Chem Soc Faraday Trans I 75:132– 139 (1979).

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